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dc.contributor.authorSemerci, Fatih
dc.contributor.authorYeşilel, Okan Zafer
dc.contributor.authorYüksel, Fatma
dc.date.accessioned2021-12-12T17:00:52Z
dc.date.available2021-12-12T17:00:52Z
dc.date.issued2015
dc.identifier.issn0277-5387
dc.identifier.urihttps://doi.org/10.1016/j.poly.2015.04.035
dc.identifier.urihttps://hdl.handle.net/20.500.11857/2954
dc.description.abstractThree new metal organic coordination architectures from one-dimensional structures to three-dimensional frameworks, formulated as [Zn(mu-HCO2)(HCO2)(mu-o-bix)](n) (1), {[Cu(mu-o-bix)(2)(H2O)(2)]center dot 2HCO(2)}(n) (2) and {[Cd-2(mu(3)-siP)(2)(mu-o-bix)(2)Cd(mu-o-bix)(2)(H2O)(2)]center dot 5H(2)O) (3) (sip = 5-sulfoisophthalate), were synthesized using the flexible 1,2-bis(imidazole-1-ylmethyl)-benzene (o-bix) ligand in mixed-solvent media (solvothermal conditions) and characterized by single-crystal diffraction, Fr-IR and photoluminescence spectroscopy and thermogravimetric/differential thermal analysis. The X-ray crystallographic studies of 1 and 2 reveal 2D layer structures involving formate ions, which are generated in situ from the hydrolysis of DMF. Topological analysis results of the complexes show that 1 displays a honeycomb-like 6(3) layer and 2 has a hydrogen-bonded 2D structure with a 4-connected (4(4).6(2)) square lattice topology. Compound 3 exhibits a 3D 4,6-connected tcj/hc (4(2).5(2).6(2))(4(2).5(6).6(4).7(3)} net. In addition, the photoluminescence spectra of 1 and 3 show blue fluorescent emission bands; these emissions can probably be assigned to intraligand fluorescent emissions. (C) 2015 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [109T201]en_US
dc.description.sponsorshipThis work has been supported by the Scientific and Technological Research Council of Turkey (TUBITAK, Project No: 109T201).en_US
dc.language.isoengen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.identifier.doi10.1016/j.poly.2015.04.035
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCoordination polymersen_US
dc.subject1,2-Bis(imidazol-1yl-methyl)benzene complexesen_US
dc.subjectHydrolysis of DMFen_US
dc.subject5-Sulfoisophthalate complexesen_US
dc.subjectSolvothermal synthesisen_US
dc.titleSelf-assembly of three new metal organic coordination networks based on 1,2-bis(imidazol-1yl-methyl)benzeneen_US
dc.typearticle
dc.authoridYESILEL, Okan Zafer/0000-0002-2284-1578
dc.departmentFakülteler, Teknoloji Fakültesi, Enerji Sistemleri Mühendisliği Bölümü
dc.departmentFakülteler, Teknoloji Fakültesi, Enerji Sistemleri Mühendisliği Bölümü
dc.identifier.volume102en_US
dc.identifier.startpage1en_US
dc.identifier.endpage7en_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.authorscopusid35782527900
dc.authorscopusid16403949600
dc.authorscopusid8621610900
dc.identifier.wosWOS:000367757100001en_US
dc.identifier.scopus2-s2.0-84942058923en_US
dc.authorwosidYESILEL, Okan Zafer/P-6633-2019


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