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One-pot synthesis of two new metal-organic networks: hydrogen bonded mononuclear Cu(II) complex and mixed-valence Cu(I,II) coordination polymer with encapsulated 14-membered unique water cluster

Semerci, Fatih; Yeşilel, Okan Zafer; Yüksel, Fatrna; Şahin, Onur (Elsevier Science Bv, 2015)

{[Cu-4(mu-bpe)(4)Cu-2(mu-pydc)(2)(mu(3)-pydc)(2)]center dot 14H(2)O}(n) (1) and [Cu(pydcH)(2)(bpe)(2)] (2) have been solvothermally synthesized by 1,2-bis(4-pyridyl)ethylene (bpe) along with dianionic pyridine-2,3-dicarboxylate ...